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    • 专利摘要:
    The invention relates to a profile made of a foamed polyvinyl chloride polymer comprising at least 40 parts per 100 parts by weight of polyvinyl chloride (PVC), preferably at least 60 parts by weight of naturally occurring mineral filler, and PVC with K value 50-58.
    公开号:BE1018321A3
    申请号:E2009/0671
    申请日:2009-10-30
    公开日:2010-08-03
    发明作者:Raf Bussels；Joseph Philip Gabriels；Christianus Johannes Spijkerman
    申请人:Tessenderlo Chemie N V S A；
    IPC主号:
    专利说明:

    Foamed PVC profiles with high mineral filler content and their use
    Technical field
    The invention relates to foamed and reinforced PVC profiles and their use. Background
    Polyvinyl chloride polymer (PVC) is a plastic that, due to its versatile physical and chemical properties, is used in all kinds of industries. There is a demand for panels from PVC to be able to replace wood and tiles in floor and wall coverings (decking and siding). For these applications it is undesirable for panels to bend or expand under the influence of heat. At the same time, these profiles, which often have large dimensions, must be easy to install.
    In US2007 / 0078191, decking was made from a PVC composition with a large amount of fiberglass and a foaming agent. The use of large amounts of glass fiber is disadvantageous. The corrosive and abrasive glass fibers abrade and damage metal machine parts. As a result, frequent repairs and replacements must be made. Damaging the mold for the production of PVC profiles causes loss of shape retention and increased rejection percentages. Because of the exposure risk associated with inhaling glass fibers, these fillers should be avoided.
    The use of alternative reinforcing fibers, such as synthetic fibers (aramid or carbon fibers), mineral fibers (fiberglass) or natural fibers (flax, wood), leads to a considerable increase in raw material costs, which makes a PVC profile unattractively expensive. In addition, these fibers considerably complicate PVC processing. A disadvantage of natural fibers, such as flax for example, is their varying composition and therefore fluctuating quality. They are moisture sensitive and can therefore mold and rot even when they are incorporated in a PVC device, such as a profile.
    Thus, there is a need for new PVC profiles. The present invention has for its object to at least partially solve the above problems.
    Summary
    The invention provides for this purpose foamed PVC profiles with a high content of a naturally occurring mineral filler and the description of their use.
    In a first aspect, the invention relates to profiles made of a foamed polyvinyl chloride polymer comprising per 100 parts by weight of polyvinyl chloride (PVC) at least 40 parts by weight, preferably at least 60 parts by weight of naturally occurring mineral filler, and PVC with K value 50-58.
    In a second aspect, the invention relates to a method for obtaining a foamed profile according to the invention.
    In a third aspect, the invention relates to a granulate or foamed profile obtained with a method according to the invention.
    In a further aspect, possible uses of these PVC profiles are described.
    In order to better show the characteristics of the invention, a few preferred embodiments are described below as an example without any limiting character.
    Description of the invention
    As used further in this text, the singular forms "one," "the," "the," include both the singular and the plural unless the context is clearly different.
    The terms "include", "includes" as used further are synonymous with "inclusive," include "or" contain, "contain" and are inclusive or open and do not exclude additional, unnamed members, elements or method steps.
    The terms "include", "includes" include the term "include".
    The enumeration of numerical values based on numerical ranges includes all values and fractions in these ranges, as well as the cited endpoints.
    The term "about" as used when referring to a measurable value such as a parameter, a quantity, a duration, and so on, is intended to encompass variations of +/- 10% or less, preferably +/- 5% or less, more preferably +/- 1% or less, and even more preferably +/- 0.1% or less, from and from the specified value, as far as the variations apply to function in the disclosed invention. It is to be understood that the value to which the term "approximately" refers per se has also been disclosed.
    All documents quoted in the current specification are fully incorporated herein by reference.
    Unless defined otherwise, all terms disclosed in the invention, including technical and scientific terms, have the meaning that those skilled in the art usually understand. As a further guide, definitions are included for further explanation of terms used in the description of the invention.
    A foaming agent is used in the preparation to obtain a PVC profile with reduced density. The term "foaming agent" in the present invention is understood to mean a chemical that decomposes gas. Polyvinyl chloride polymer is mixed with a foaming agent. This mixture is fed as raw material to an extruder. In the extruder the foaming agent and raw material are heated to a melt The heating causes a decomposition of the foaming agent When leaving the extruder, the melt experiences a pressure reduction and is foamed.
    Foaming is more annoyed as a preparation is strengthened. In the present invention, "reinforced" means that reinforcing materials have been added to a preparation. As a result, a reinforced material is obtained. A foaming agent is added to an extruder together with a reinforcing material. They can be dosed simultaneously or separately.
    The inventors have succeeded in producing a foamed and reinforced profile from a polyvinyl chloride polymer comprising at least 40 parts by weight per 100 parts by weight of polyvinyl chloride (PVC), preferably at least 60 parts by weight of a naturally occurring mineral filler per 100 parts by weight of polyvinyl chloride (PVC).
    The term "phr" as used in the present invention is understood to mean "parts per hundred resin". The use of this unit is based on 100 parts of polyvinyl chloride polymer and the amount of other ingredients is expressed with respect to this 100 parts of polyvinyl chloride polymer. In the present invention, the term "highly filled" is understood to mean a high content of naturally occurring mineral filler. A profile is highly filled from 25 phr naturally occurring mineral filler. The highly filled PVC profiles were of good quality, homogeneous composition, without bulging fillers on the surface. They were not hindered by mixing or foaming problems.
    The term "naturally occurring mineral filler" is understood to mean a filler that can be found as such in nature and that can be used with the exception of grinding without the use of a synthesis process. The designation mineral indicates that it is an element or chemical compound that is usually crystalline and that was formed as a result of geological processes. Glass fibers are excluded by the definition as they require a synthesis step starting from SiO2. Wood fibers are not mineral.
    In the present invention, the term "naturally occurring mineral filler" is especially understood to mean silica, wollastonite, vermiculite, talc, mica and / or combinations thereof. In a preferred embodiment of the invention, the naturally occurring mineral filler is selected from a group comprising wollastonite, vermiculite, talc, mica and / or combinations thereof. In a preferred embodiment of the invention, the naturally occurring mineral filler in a profile is talc and / or mica. If a rigid profile is desired, mica is preferred. If a profile is desired with a reduced linear thermal expansion coefficient, talc is preferred.
    That considerable reinforcement can be obtained with only a naturally occurring mineral filler is unusual since it is generally assumed that in order to obtain substantial reinforcement, fiber materials must be used. In the present invention, the term "fiber materials" is understood to mean glass fibers, aramid fibers, carbon fibers and / or combinations thereof.
    In a preferred embodiment, PVC is used with a K value between 50 and 68. The "K value" of a polymer is a measure of the molecular weight and is based on the inherent viscosity. A K value between 50 and 68 corresponds to a weight average molecular weight of approximately 40000-100000 g / mol. In a more preferred embodiment, the polyvinyl chloride polymer has a K value between 50 and 60. In a most preferred embodiment of the invention, the PVC has a K value between 50 and 58. A K value of 57 is advantageous for good processability. and mechanical properties. PVC is commercially available as a powder. The PVC can be used in the form of regenerate (scrap). The term "regenerate (scrap)" as used in the present invention is understood to mean recyclable PVC-based materials from the starting or stopping of extrusion lines, or PVC-based material outside of specification. In a preferred form, a method comprises extruding a formulation comprising at least 10% by weight of regenerate.
    The invention thus provides profiles made from a foamed polyvinyl chloride polymer comprising at least 40 parts by weight of naturally occurring mineral filler per 100 parts by weight of polyvinyl chloride (PVC) and PVC with a K value of 50-58. In a more preferred embodiment, the profiles comprise at least 50 parts by weight of naturally occurring mineral filler per 100 parts by weight of polyvinyl chloride, and PVC with K value 50-58. In a more preferred embodiment, the profiles comprise at least 60 parts by weight of naturally occurring mineral filler per 100 parts by weight of polyvinyl chloride, and PVC with K value 50-58.
    In a preferred embodiment, the naturally occurring mineral filler is talc and / or mica. Talc is a hydrated magnesium silicate, with the chemical structural formula Mg3Si4O10 (OH) 2. For application, it is ground to powder with an average grain size between 0.5 µm and 20 µm. It is commercially available. Mica is preferably of the muscovite type, this is a phyllosilicate mineral, with the chemical structural formula KAl2 (AISi3O10) (OH, F) 2. For use, it is ground to powder with an average grain size between 0.5 µm and 40 µm. It is commercially available. This feature has the advantage that the PVC profiles have improved fire-resistant properties, a reduced thermal expansion, and a higher rigidity. This is an interesting feature for use in building components. The invention thus provides profiles from PVC, characterized in that the naturally occurring mineral filler is talc and / or mica.
    In a preferred embodiment of the invention, the naturally occurring mineral filler is talc and / or mica with an average grain size between 0.5 and 5 µm. In a more preferred embodiment, the naturally occurring mineral filler is talc and / or mica with an average grain size between 0.5 and 3 µm for talc and between 30 and 35 µm for mica. Preferably, the granules are elongated in shape and are platelets. The average grain size d50 of a naturally occurring mineral filler can be determined by measurement techniques known to those skilled in the art. For example, using the method described in ISO 13320.
    In a preferred embodiment, a profile has a linear thermal expansion coefficient (CLTE) lower than 25 x 10 "6 mm / mm / K. In a more preferred embodiment, a profile has a linear thermal expansion coefficient lower than 20 x 10-6 mm / mm / K. In a most preferred embodiment, a profile has a linear thermal expansion coefficient lower than 15 x 10 -6 mm / mm / K. The term "linear thermal expansion coefficient", also abbreviated as CLTE, describes how much a material will expand for each increment in temperature change, as represented by formula:
    where d1 = the change in length of the material in the measuring direction, 10 = initial length of the material in the measuring direction, dT = change in temperature over the interval d1 over which measurement is made.
    Linear thermal expansion coefficients can be measured by techniques known to those skilled in the art. For example, linear thermal expansion coefficients can be determined by means of a silica dilatometer according to ASTM D 696 or ISO 11359. This feature has the advantage that the profiles are less susceptible to shrinking and expansion under the influence of temperature. This is advantageous in applications where PVC profiles are exposed to weather conditions, for example in cladding of facades, terrace floors, shutters with slats in windows and doors (shutters). Thus the invention provides PVC profiles, preferably with a linear thermal expansion coefficient lower than 25 x 10 -6 mm / mm / K, more preferably lower than 20 x 1CT6 mm / mm / K, most preferably lower than 15 x 10 -6 mm / mm / K.
    In a preferred embodiment, a profile has a density, expressed in kg / l, below 1.0, preferably between 0.6 and 0.8, more preferably about 0.6. A low density is an advantage for applications where lightweight structures are required, such as covering walls with plastic panels.
    In a preferred embodiment, a profile is provided with a non-foamed outer body and a foamed inner body. Such a structure is advantageous to arrive at a lightweight material. This property is important in applications where lightweight materials are used, such as the use of profiles as wall cladding (sidings). In contrast to full façade cladding, a lightweight construction, due to its lower density and / or availability of small spaces, provides an easy installation. One person can suffice to install panels.
    In a preferred embodiment, a profile was created with a raw material obtained by two mixing steps; each mixing step involves mixing PVC with a naturally occurring mineral filler and a temperature treatment. Eligible mixing steps are traditional preparation steps such as compounding, granulating, extruding, injection molding. More information about these preparations can be found in manuals such as, for example, PVC Handbook, Eds. Charles E. Wilkes, James W. Summers, and Charles A. Daniels, published by Hanser Gardner, 2005.
    In a preferred embodiment, in the first mixing step, an amount A of the naturally occurring mineral filler is mixed with PVC at a temperature lower than the melting temperature of the PVC; and in a second mixing step an amount B of the naturally occurring mineral filler is mixed with the first mixture and a foaming agent in a concentration between 0.1 and 5% at a temperature higher than 180 ° C.
    Unlike other plastics, polyvinyl chloride does not have one specific melting temperature, but rather a melting range ranging from 130 ° C to 240 ° C. By "temperature lower than the melting temperature" of a polyvinyl chloride polymer, a temperature lower than 130 ° C is meant. In a preferred method according to the invention, the temperature in the second mixing step is preferably 185 ° C, more preferably 190 ° C, even more preferably 195 ° C and most preferably 200 ° C. In a more preferred embodiment of the invention, a PVC profile is obtained by extruding in the second mixing step at a temperature of preferably 185 ° C, more preferably 190 ° C, even more preferably 195 ° C and most preferably 200 ° C.
    The filler that is used in the first mixing step can differ from the filler that is used in the second mixing step. A foaming agent is used to foam a profile. The foaming agent added to reduce the density of the PVC-R profile may be of the sodium (bi) carbonate, azodicarbonamide or OBSH (p, p'-oxybis (benzene sulfonyl jhydrazide) type. Preferably an azodicarbonamide is used , because of the good price-performance balance The foaming agent can be dosed together with the naturally occurring mineral filler or separately to an extruder.This preparation has the advantage that the homogeneity is preserved, so that problems such as demixing and loss of quality are reduced. The invention thus provides profiles, characterized in that raw material for the profile is obtained by two mixing steps for mixing the PVC with naturally occurring mineral fillers, preferably the naturally occurring mineral filler is talc and / or mica. More preferably, the naturally occurring mineral filler is talc, most preferably the naturally occurring mineral filler talc with an average grain size d50 between 0.5 and 20 Mm.
    The advantage of this preparation is that the amount of filler can be increased without the processability being compromised. The resulting profiles are of good quality. For example, the profiles have a smooth and homogeneous surface, with no protruding filler parts on their surface. The use of a naturally occurring mineral filler over fibers has the advantage that they are cheaper and readily available. Glass fibers are abrasive, so machine parts are damaged. If the cylinder of an extruder is damaged or the profile die is scratched, the dimensional stability of the profiles produced decreases and there is a high repair and failure costs. The invention thus provides profiles characterized in that in their preparation, in a first mixing step, an amount A of the naturally occurring mineral filler is mixed with PVC at a temperature lower than the melting temperature of the PVC; and that in a second mixing step an amount B of the naturally occurring mineral filler is mixed with the first mixture and a foaming agent in a concentration between 0.1-5% at a temperature higher than 180 ° C.
    In a preferred embodiment, a method for producing a foamed profile according to the invention comprises the steps of: a) preparing a pre-reinforced polymer by mixing a polyvinyl chloride polymer with an amount A of a naturally occurring mineral filler and with 0.1 to 5% by weight foaming agent, at a temperature lower than the melting temperature of the Polyvinyl chloride polymer; b) mixing the pre-reinforced polymer obtained under a) with an amount B of a naturally occurring mineral filler at a temperature higher than 180 ° C into a reinforced Polyvinyl chloride polymer, c) optionally granulating the reinforced Polyvinyl chloride polymer obtained in step b), d) pressing the reinforced polyvinyl chloride polymer obtained in step b) or the granulate obtained in step c) through a mold to obtain the foamed profile.
    In another preferred embodiment, a method for producing a foamed profile according to the invention comprises the steps of: a) preparing a pre-reinforced polymer by mixing Polyvinyl chloride polymer with an amount A of a naturally occurring mineral filler , at a temperature lower than the melting temperature of the polyvinyl chloride polymer; b) mixing the pre-reinforced polymer obtained under a) with an amount B of a naturally occurring mineral filler and with 0.1 to 5% by weight foaming agent, at a temperature higher than 180 ° C to a reinforced Polyvinyl chloride polymer, c) optionally granulating the reinforced polyvinyl chloride polymer obtained in step b), d) pressing the reinforced polyvinyl chloride polymer obtained in step b) or the granulate obtained in step c) through a mold to obtain the foamed profile.
    In another preferred embodiment, a method for producing a foamed profile according to the invention comprises the steps of: a) preparing a pre-reinforced polymer by mixing a polyvinyl chloride polymer with an amount A of a naturally occurring mineral filler , at a temperature lower than the melting temperature of the polyvinyl chloride polymer; b) mixing the pre-reinforced polymer obtained under a) with an amount B of a naturally occurring mineral filler, at a temperature higher than 180 ° C, into a reinforced Polyvinyl chloride polymer, c) granulating the reinforced Polyvinyl chloride polymer obtained in step b), d) mixing the granulate obtained in step c) with 0.1 to 5% by weight foaming agent, and pressing the resulting mixture through a mold at a temperature higher than 180 ° C to obtain the foamed profile.
    In a preferred form of the above process, the amount of A of a naturally occurring mineral filler is between 0-2 phr, between 2-25 phr or between 25-40 per hundred parts of Polyvinyl chloride polymer (phr). In a production environment where the processing equipment is close to the mixer, an amount of A between 25-40 phr is advantageous, since there is little transport. For situations with an average transport requirement, an amount of A between 2-25 phr is an advantage. With excellent dosing systems, the amount of A can be reduced to 0-2 phr. In a preferred embodiment, a highly filled compound is formed in the first step by using at least 25 parts by weight of naturally occurring mineral filler.
    In a preferred embodiment, a highly filled compound is formed in the first step by using at least 10 parts by weight of naturally occurring mineral filler. In a more preferred embodiment, at least 30 parts by weight of naturally occurring mineral filler is used in the first step. In a most preferred embodiment, at least 40 parts by weight of filler are used in the first step. A pre-reinforced polymer is formed by heating at a temperature lower than the melting temperature of the PVC. The foaming agent can be added in a first step or can only be added with the addition of the second amount of filler. It can be dosed together or separately with the filler to an extruder. However, the foam is not hindered. This has the advantage that reinforced and foamed profiles are obtained. The invention thus provides PVC profiles, characterized in that preferably at least 10 parts by weight, more preferably at least 30 parts by weight, most preferably at least 40 parts by weight naturally occurring mineral filler are used in the first mixing step.
    The ratio of the first amount A of a filler to the second amount B of a filler is at least 0.1, preferably at least 0.2, more preferably at least 0.25, most preferably at least 0.3. If this ratio is used in the preparation of a feed from an extruder, it will show an almost optimum flow and compressibility. This is unexpected since it is known that highly filled compositions are difficult to flow through the fill opening in a cylinder of an extruder and do not flow fast enough to properly fill the first passages of a screw. This leads to incomplete mixing and poor quality of the end product. It is also known that a highly filled composition has a very high compressibility. A screw of an extruder can therefore compact the feed to a limited extent, insufficient to generate the required friction to melt the material. As a result, a powder or product that is only sintered comes out of the extruder, instead of a good melt. The invention thus provides PVC profiles, characterized in that the ratio A over B is at least 0.1, preferably at least 0.2, more preferably at least 0.25, most preferably at least 0.3.
    In a preferred embodiment, the total amount of filler is in weight%, up to 70% of the reinforced polyvinyl chloride polymer. The usability of larger quantities of filler offers more possibilities for controlling product properties, for example the reduction of the linear thermal expansion coefficient.
    In a preferred embodiment, the total number of parts filler (A + B) is opposite the number of parts Polyvinyl chloride polymer, preferably between 0.4 and 2.5, more preferably between 0.6 and 1.5, most preferably between 0.8 and 1.2. In a preferred embodiment, the total amount of naturally occurring mineral filler (A + B) is opposed to the amount of Polyvinyl chloride polymer, preferably between 0.4 (about 30% by weight amount of naturally occurring mineral filler / 70% by weight PVC) and 2.5 ( about 70% by weight amount of naturally occurring mineral filler / 30% by weight PVC), more preferably between 0.6 and 1.5, most preferably between 0.8 and 1.2. This ratio has the advantage that sufficient polymer is present in comparison with naturally occurring mineral filler for good melting and mixing in an extruder, resulting in a homogeneous mixture. This ratio has the advantage that sufficient polymer is present versus filler for good melting and mixing in an extruder, resulting in a homogeneous mixture. In a preferred embodiment, the total amount of naturally occurring mineral filler (A + B) is opposed to the amount of polyvinyl chloride polymer in a method for the preparation of a device according to the invention, preferably between 0.4 and 2.5, more preferably between 0.6 and 1.5, most preferably between 0.8 and 1.2.
    In a preferred embodiment, a PVC profile comprises at least one auxiliary substance selected from a group comprising heat stabilizers, lubricants, processing aids, impact stabilizers, light stabilizers, colorants. In a preferred embodiment according to the invention, the excipients in a formulation consist of a heat stabilizer, a lubricant and a processing excipient. No further additives are required.
    In a preferred embodiment, a heat stabilizer is selected from a group of CaZn, Ca-organic, Sn, or Pb stabilizers. Type CaZn refers to calcium-zinc systems based on fatty acid salts of calcium and zinc in combination with cost stabilizers. Type Ca organic means stabilizers based on fatty acid salts of calcium in combination with cost stabilizers. Type Sn means stabilizers based on organotin compounds. Type Pb refers to stabilizers based on (in) organic lead salts. A heat stabilizer causes the dehydrochlorination process of Polyvinyl chloride to be delayed and prevents Polyvinyl chloride from burning during a heat treatment such as extruding. For use in Europe, there is a preference for CaZn and Ca-organic heat stabilizers. For use in North America, there is a preference for Sn stabilizers. The reasons for this are historical. North America has always preferred Sn, while Europe has always preferred Pb stabilizers. As Pb stabilizers will disappear (at the latest in 2015), the preference in Europe is now for CaZn and Ca-organic.
    In another embodiment of the invention, the heat stabilizer is a blocked thiol type heat stabilizer. By the term "blocked thiol type" heat stabilizer is meant a thiol of formula B-S-R wherein B and R represent an organic portion. Blocked thiols and organic-based heat stabilizers are interchangeable as terms. An organic-based heat stabilizer comprises a zinc salt, and at least one sulfur compound selected from the group consisting of a free mercaptan, a zinc mercaptide, and a latent mercaptan. Preferably, an organic-based heat stabilizer is an organic-based composition comprising at least one organic-based heat stabilizer component, and at least one stabilizer modifying compound selected from the group comprising a liquid calcium soap and 1,3,5-tris (2- hydroxyethyl cyanuric acid; wherein the organic-based heat stabilizer component comprises a zinc salt and at least one sulfur compound selected from the group consisting of a free mercaptan, a zinc mercaptide, and a latent mercaptan; and wherein the liquid calcium salt is a solution of a calcium salt that is liquid at 105 ° C and free from other metal salts.
    Use of a blocked thiol type stabilizer system is advantageous since it is substantially free of heavy metals and harmful bisphenol A co-stabilizer. It is a more environmentally friendly type of stabilizer. An additional advantage is that this type of stabilizer is a recycling booster. PVC stabilized with a blocked thiol-type stabilizer is compatible with other stabilization systems such as the CaZn, Ca-organic or Sn-type stabilizers. It can be safely combined with recycled PVC. It delivers good color stability to PVC profiles. In a preferred form of the invention, a profile comprises up to 10% by weight of recycled PVC; preferably up to 25% by weight recycled PVC, comprising a blocked thiol type stabilizer.
    In a preferred embodiment, the total amount of stabilizers in a formulation is preferably between 1 to 4% by weight, more preferably between 2 and 4% by weight, most preferably between 3 and 4% by weight. In a more preferred embodiment of the invention, the total amount of stabilizers in a formulation is a maximum of 1.5% by weight when using stabilizers of the Sn type, 5% by weight when using stabilizers of the Pb type, 2-4% by weight when using Ca / Zn or Ca-organic-organic stabilizers, 4% by weight when a blocked thiol type is used.
    In a preferred embodiment of the invention, a method further comprises the step of: adding a thermal stabilizer in an amount between 0 and 5% by weight; preferably between 1 and 4% by weight; wherein the thermal stabilizer is preferably a blocked thiol type stabilizer.
    A lubricant is used, for example, to promote the flow of a polymer melt through a processing device such as an extruder. In a preferred embodiment, a lubricant is selected from a group comprising polyethylene waxes, oxidized polyethylene waxes, paraffin waxes, fatty acid ester waxes (e.g. distearyl phthalate), salts of fatty acids (e.g. calcium stearate), fatty acids, fatty acid alcohols, amine waxes and / or combinations thereof. In a preferred embodiment, the total amount of lubricants in a formulation is preferably between 0 and 2% by weight, more preferably between 1 and 2% by weight, most preferably between 1.5 and 2% by weight.
    In a preferred embodiment, a processing aid is selected from a group comprising methacrylate copolymers, acrylate copolymers, methacrylate terpolymers, acrylate terpolymers and / or a combination thereof. In a preferred embodiment, the total amount of processing aid in a formulation is preferably between 0 and 15% by weight, more preferably between 5 and 15% by weight, most preferably between 10 and 15% by weight. This use, for example, supports the processability of a polymer by promoting fusion, improves melt strength, changes surface properties, ensures better release of a formulation of metal parts.
    In addition to polyvinyl chloride polymer and naturally occurring mineral filler, a formulation may also comprise one or more excipients. In an embodiment of the invention, a method comprises the step of adding a processing aid is used in an amount between 0 and 15% by weight; preferably between 5 and 15% by weight.
    To improve the impact resistance of an end product, an impact protector can be added to a formulation. In a preferred embodiment of the invention, the total amount of impact fasteners is preferably between 0 and 5% by weight, more preferably between 1 and 5% by weight, most preferably between 2 and 5%.
    A light stabilizer can be added to inhibit the degradation of PVC by the influence of light. In a preferred embodiment, a light stabilizer is selected from a group comprising a stabilizer of the type titanium dioxide, type benzotriazole, type 2-hydroxybenzophenone and / or combinations thereof. In a more preferred embodiment of the invention, titanium dioxide is used. In a most preferred embodiment, the total amount of light stabilizers in a formulation is preferably between 0 and 10% by weight, more preferably between 2 and 8% by weight, most preferably between 4 and 6% by weight.
    A foamed profile according to the invention can be provided with a covering layer or cap. The coating material is selected from a group comprising poly ((meth) acrylate), poly (butyl acrylate-styrene-acrylonitrile), polyvinylidene fluoride, polyvinyl fluoride, poly (styrene-acrylonitrile), a light-resistant polyvinyl chloride material and / or a combination thereof. In a preferred embodiment of the invention, the total amount of coating additive in a formulation is preferably between 0 and 6% by weight, more preferably between 0 and 4% by weight, most preferably between 0 and 2% by weight.
    If no cover layer (cap) will be extruded over a PVC profile, a profile is colored in by means of a dye. In a preferred embodiment, a colorant is selected from a group comprising a metal salt, metal oxide, mixed metal oxide and / or combinations thereof. In a more preferred embodiment, a mixed metal oxide is used. This shows the best aging behavior. In a preferred embodiment, the total amount of colorants in a formulation is preferably between 0 and 5% by weight, more preferably between 1 and 4% by weight, most preferably between 2 and 3% by weight.
    In an additional aspect, the invention provides a reinforced polyvinyl chloride polymer based on a formulation comprising: polyvinyl chloride polymer in an amount that is preferably between 30 and 70, more preferably between 35 and 70, most preferably between 40 and 70 weight% of the formulation; and a naturally occurring mineral filler in an amount that is preferably between 30 and 70% by weight, more preferably between 35 and 70% by weight, most preferably between 40 and 70% by weight of the formulation.
    In a preferred form of the invention, a reinforced polyvinyl chloride polymer is based on a formulation comprising: polyvinyl chloride polymer in an amount of at least 30% by weight, preferably at least 35% by weight, more preferably at least 40% by weight, most preferably at least 45% by weight of the formulation; and a naturally occurring mineral filler in an amount of at least 30% by weight, preferably at least 35% by weight, more preferably at least 40% by weight, most preferably at least 45% by weight of the formulation.
    In a preferred form of the invention, a reinforced polyvinyl chloride polymer is based on a formulation comprising: Polyvinyl chloride polymer in an amount of at least 30% by weight, preferably at least 35% by weight, more preferably at least 40% by weight, most preferably at least 45% by weight of the formulation; and a naturally occurring mineral filler in an amount of at least 30% by weight, preferably at least 35% by weight, more preferably at least 40% by weight, most preferably at least 45% by weight of the formulation; wherein the naturally occurring mineral filler is talc and / or mica, preferably talc.
    A polyvinyl chloride polymer based on a formulation according to a preferred embodiment of the invention contains elevated naturally occurring mineral filler levels. These highly filled polyvinyl chloride polymers are heavier reinforced, have increased fire retardant properties, increased toughness, increased rigidity.
    In a further aspect, the invention provides a granulate or profile obtained with a method as previously described. In a further aspect the invention provides a parts kit comprising a granulate according to the invention and a foaming agent. In a further aspect of the invention, uses of the PVC profiles are provided.
    The profiles according to an embodiment of the invention are preferably used as a panel. In a preferred embodiment, the profiles are used in floor or wall cladding, such as, for example, in a terrace floor or a house facade cladding. Traditionally, exterior floors, such as terraces, are covered with tiles, wooden planks or wood-plastic composite planks. The exterior facade of a house is traditionally clad in brick, stucco, wood, PVC or aluminum. Replacement of traditional building materials with a panel according to the invention has the advantage that the panel is insensitive to moisture, rot, mold and discoloration under the influence of sunlight. Furthermore, a panel according to the invention is light yet strong. It is less sensitive to heat distortion. Because it will expand / shrink less, the panels will not be bent. With a weight load, the panels bend less. The panels are easy to maintain. They have an improved insulation value compared to non-foamed panels. This provides extra insulation on a facade. PVC profiles according to a preferred form of the invention do not bend at elevated temperature. This makes the PVC profiles suitable for interior and exterior use, preferably in floor, wall or façade cladding. PVC profiles according to a preferred form of the invention are sturdy, light and well-insulating material. PVC profiles according to a preferred form of the invention are recyclable. The invention thus provides for a use of a profile according to a preferred embodiment, as a panel, preferably in a floor or wall covering.
    In a preferred embodiment, a panel is provided with a closing mechanism, preferably in the form of a tongue and groove with the tongue and groove forming a connection for joining together profiles. This makes easier manipulation and placement possible. The invention thus provides for a use of a panel provided with a closing mechanism, preferably in the form of a tongue and groove, the tongue and groove forming a connection for joining together profiles.
    PVC profiles according to a preferred form of the invention are easily processable. They can be machined with standard joiner's tools such as a saw or drill. They can be nailed or nailed without the profile cracking or splintering. The use of clips or hooks can be avoided. In addition, profiles in which no glass fiber was used have the advantage that no harmful silica dust is generated when a profile is cut.
    A profile according to an embodiment of the invention has the advantage that it can be provided with a gutter that serves as a strip for the profile's heating. A profile can be hammered straight through the gutter and thus provide a firm attachment to a wall when applying cladding. The nailing process can be accelerated by the use of a nail gun. In a preferred embodiment, a panel is attached to a surface such as a floor or wall using a nail, preferably a nail gun.
    In a preferred embodiment, a panel is a slat of a hatch. In the present invention, "hatch" is understood to mean a window, door, or fence that includes panels mounted at an angle so that light and air are admitted but direct sunlight and rain are kept out. Shutter is a synonym. The angle is usually fixed when mounting the panels in a window, door or fence, but can also be adjustable. The invention thus provides a use of a panel in an embodiment of the invention as a slat in a hatch. The panels according to the invention are light yet strong and tough, so that when used as a slat in a hatch, a strong construction is formed that is light, so that, for example, a window hatch is easy to lift and assemble.
    Profiles according to an embodiment of the invention can easily be aligned against the exterior wall of a building. It is not necessary to provide clearance between panels to allow expansion and contraction of the panel.
    It is self-evident that the description of this invention within its scope may relate to alternative embodiments. The invention is illustrated by the following non-limitative examples.
    PVC Profiles Examples 1-6
    Profiles according to a preferred form of the invention may be based on compositions as shown in Tables 1 and 2.
    For the preparation of a batch quantity of 100 kg, the following quantities were introduced into a Periplast brand hot mixer with a tank volume of 250 liters: 100 parts Polyvinyl chloride polymer, 1.5 parts Sn stabilizer, 1.9 parts lubricants, 12 parts processing aid and 25 to 60 parts of talk. The ingredients were mixed by means of a stirrer with tip speed 38 m / s. The jacket temperature was 80 ° C. Upon reaching a temperature of 120 ° C, the mixture was overflowed. The mixture was placed in a Periplast brand cold mixer with a tub volume of 800 liters. The mixture was stirred at a tip speed of 6 m / s. The jacket temperature was set to 10 ° C to cool the mixture. The mixture was cooled until an overflow temperature of 40 ° C was reached.
    Table 1: Compositions for creating PVC profiles for facade cladding
    (*) 25 phr added in the hot mixer, 35 parts added on the extruder.
    (**) Added on the extruder.
    Table 2: Compositions for creating PVC profiles for terrace floors (decking) or for (roller) shutters (shutters)
    (*) 40 phr added in the hot mixer, 20 parts added on the extruder.
    (**) Added on the extruder.
    The thus obtained pre-reinforced polymer was introduced into a metering unit of a counter-rotating parallel twin screw extruder of the Bandera brand. A foaming agent in a concentration of 1.5-2% was added. For the production of decking and shutters (examples 3 and 4), 6 parts of impact-resistant were added. In Example 4, 9 parts of light stabilizer were also added. The resulting mixture was processed in the extruder to form granules or directly to a profile using a mold. A typical example of a profile extrusion (Example 5) is shown in Table 3. The composition from Example 3 resulted in a coated profile applied by co-extrusion.
    Table 3: Typical example of a direct profile extrusion.

    (*) 20D = 20x screw diameter
    In order to further illustrate the invention, facade panels as described by Example 5 were prepared. To make a 100 kg batch, the ingredients as listed in Table 4 were used. PVC with a K value 57, titanium dioxide, tin-based stabilizer, lubricants and processing aids were loaded in a warm mixer at room temperature. These ingredients were mixed using a stirrer with a tip speed of 38 m / s. The jacket temperature of the heat mixer was adjusted to heat up the mixture of ingredients. Upon reaching 120 ° C in the mixture, a first amount of talc A was added to the heat mixer and stirred continuously. Upon reaching a temperature of 120 ° C, the mixture was transferred to a cold mixer. The mixture was stirred at a tip speed of 6 m / s. The jacket temperature was set to 15 ° C to cool the mixture. The mixture was cooled until an overflow temperature of 40 ° C was reached.
    Table 4: Composition for producing PVC sidings
    The compound thus obtained was transported by means of transport lines to a mixing station (hopper + feed) of an extruder. The used extruder was a counter-rotating conical twin-screw extruder of the Krauss-Maffei KMD60 type. From this feed the compound flowed onto the screws of the extruder. By means of a second dosing installation (hopper + feed) on the extruder, the remaining amount of talc, amount B, was added. By means of two additional dosing stations, the foaming agent and the additives were added on-line. The material flows came together on the screws of the extruder. The conditions used for the extruder are shown in Table 5.
    On the screws of the extruder, the compound was heated to above the melting temperature of PVC. The material melted and intensive mixing took place. The foaming agent dissolved chemically into inert gas (nitrogen, CO2). Due to the high melt pressure, the gases remained dissolved in the melt. The melt was transported by means of the screws from extruder to a mold. The melt flow was pressed through the mold. The mold that was used had the shape and size of the desired profile. The melt was pushed through the mold and assumed the shape imposed by the mold. When leaving the mold, a pressure drop occurred. The inert gases from the foaming agent no longer remained dissolved in the melt and a foamed structure was formed.
    Using a second extruder (co-extruder), a cover layer was melted and brought to the mold from the main extruder. The cover layer forms a thin layer of UV-stable acrylic coating on top of the profile in the mold. After leaving the mold, the foamed and covered melt was sent to a calibration and cooling installation, where the melt was brought to the final dimensions and cooled.
    Pieces of the desired length were cut from the extruded product. This provides foamed and reinforced PVC elements for use as wall panels. In a final step, the profiles were sent through an embossing installation where a wood structure is pressed into the top of the profiles with an embossing roll. The wall cladding profiles are ready for use and can be nailed to a wall as such.
    Table 5: Extrusion conditions
    Properties PVC profiles
    Properties of PVC profiles are shown in Table 6.
    With PVC profiles made with a formulation from Example 6, a linear thermal expansion of 11x10-6 mm / mm / K and a flexural modulus of 2.5 GPa was measured.
    Table 6: Properties of PVC profiles
    权利要求:
    Claims (20)
    [1]
    Profile made from a foamed polyvinyl chloride polymer comprising per 100 parts by weight of polyvinyl chloride (PVC) at least 40 parts by weight, preferably at least 60 parts by weight of naturally occurring mineral filler, and PVC with K value 50-58.
    [2]
    Profile according to claim 1, characterized in that the naturally occurring mineral filler is selected from a group comprising wollastonite, vermiculite, talc, mica and / or combinations thereof.
    [3]
    Profile according to claim 1 or 2, characterized in that the naturally occurring mineral filler is talc and / or mica.
    [4]
    Profile according to claim 3, characterized in that the naturally occurring mineral filler has an average grain size d50 of between 0.5 and 50 µm; wherein talc preferably has an average grain size d50 between 0.5 and 5 µm and mica has an average grain size d50 between 30 and 35 µm.
    [5]
    Profile according to one of claims 1-4, with a linear thermal expansion coefficient (CLTE) lower than 25 x 10 -6 mm / mm / K, preferably lower than 15 x 10 -6 mm / mm / K.
    [6]
    Profile according to any of claims 1-5, wherein the profile has a density, expressed in kg / l, below 1.0, preferably between 0.6 and 0.8, more preferably about 0.6.
    [7]
    Profile according to any of claims 1-6, wherein the profile is provided with a non-foamed outer body and a foamed inner body.
    [8]
    A method for producing a foamed profile according to any one of claims 1-7, comprising the steps of: a) preparing a pre-reinforced polymer by mixing a polyvinyl chloride polymer with an amount A of a naturally occurring mineral filler and with 0.1 to 5% by weight foaming agent, at a temperature lower than the melting temperature of the Polyvinyl chloride polymer; b) mixing the pre-reinforced polymer obtained under a) with an amount B of a naturally occurring mineral filler at a temperature higher than 180 ° C into a reinforced Polyvinyl chloride polymer, c) optionally granulating the reinforced Polyvinyl chloride polymer obtained in step b), d) pressing the reinforced polyvinyl chloride polymer obtained in step b) or the granulate obtained in step c) through a mold to obtain the foamed profile.
    [9]
    A method for producing a foamed profile according to any one of claims 1-7, comprising the steps of: a) preparing a pre-reinforced polymer by mixing a polyvinyl chloride polymer with an amount A of a naturally occurring mineral filler, at a temperature lower than the melting temperature of the polyvinyl chloride polymer; b) mixing the pre-reinforced polymer obtained under a) with an amount B of a naturally occurring mineral filler and with 0.1 to 5% by weight foaming agent, at a temperature higher than 180 ° C to a reinforced Polyvinyl chloride polymer, c) optionally granulating the reinforced polyvinyl chloride polymer obtained in step b), d) pressing the reinforced polyvinyl chloride polymer obtained in step b) or the granulate obtained in step c) through a mold to obtain the foamed profile.
    [10]
    A method for producing a foamed profile according to any one of claims 1-7, comprising the steps of: a) preparing a pre-reinforced polymer by mixing a polyvinyl chloride polymer with an amount A of a naturally occurring mineral filler, at a temperature lower than the melting temperature of the polyvinyl chloride polymer; b) mixing the pre-reinforced polymer obtained under a) with an amount B of a naturally occurring mineral filler, at a temperature higher than 180 ° C, into a reinforced Polyvinyl chloride polymer, c) granulating the reinforced Polyvinyl chloride polymer obtained in step b), d) mixing the granulate obtained in step c) with 0.1 to 5% by weight foaming agent, and pressing the resulting mixture through a mold at a temperature higher than 180 ° C to obtain the foamed profile.
    [11]
    A method according to any one of the preceding claims 8-10, characterized in that the amount of A is between 0-2 phr or between 2-25 phr or between 25-40 per hundred parts of the Polyvinyl chloride polymer (phr).
    [12]
    A method according to any one of the preceding claims 8-11, characterized in that the ratio of the amount of A over the amount of B is at least 0.1, preferably at least 0.2, more preferably at least 0.25, most preferably at least 0.3.
    [13]
    The method according to any of claims 8 to 12, characterized in that the total amount of naturally occurring mineral filler (A + B) versus the amount of polyvinyl chloride polymer is preferably between 0.4 and 2.5, more preferably between 0.6 and 1.5, most preferably between 0.8 and 1.2.
    [14]
    A method according to any one of claims 8-13 above, characterized in that the method comprises the step of: adding a processing aid is used in an amount between 0 and 15% by weight; preferably between 5 and 15% by weight.
    [15]
    A method according to any one of the preceding claims 8-14, characterized in that the method comprises the step of: adding a thermal stabilizer in an amount between 0 and 5% by weight; preferably between 1 and 4% by weight; most preferably about 4% by weight, wherein the thermal stabilizer is preferably a blocked thiol type stabilizer.
    [16]
    A granulate or profile obtained by a method according to any of the claims 8-15 above.
    [17]
    The kit of parts comprising the granulate according to claim 16 and a foaming agent.
    [18]
    Use of a profile according to any of the claims 1-7 or claim 16 above as a panel, preferably in a floor or wall covering or hatch.
    [19]
    Use of a profile according to claim 18, wherein the panel is attached to a surface such as a floor or wall using a nail, preferably a nail gun.
    [20]
    Use of a profile according to claim 18, wherein the panel is provided with a closing mechanism, preferably in the form of a tongue and groove, the tongue and groove forming a connection for joining together profiles.
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    同族专利:
    公开号 | 公开日
    BE1018453A3|2010-12-07|
    WO2010049530A2|2010-05-06|
    WO2010049530A3|2010-06-24|
    EP2346932B1|2018-12-05|
    EP2346932A2|2011-07-27|
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    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    US11029208P| true| 2008-10-31|2008-10-31|
    BE200800595|2008-10-31|
    BE2008/0595A|BE1018453A3|2008-10-31|2008-10-31|FOAMED PVC PROFILES WITH HIGH LEVEL OF MINERAL FILLER AND THEIR USE.|
    US11029208|2008-10-31|
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